Venezuela was represented at the 2000 Summer Olympics in Sydney, New South Wales, Australia by the Venezuelan Olympic Committee.
In total, 50 athletes including 36 men and 14 women represented Venezuela in 17 different sports including athletics, boxing, cycling, diving, fencing, gymnastics, judo, sailing, shooting, swimming, sychronized swimming, table tennis, taekwondo, tennis, triathlon, weightlifting and wrestling.
Competitors
In total, 50 athletes represented Venezuela at the 2000 Summer Olympics in Sydney, New South Wales, Australia across 17 different sports.
{| class="wikitable sortable" style="text-align:center;"
|-
! width=180|Sport
! width=55|Men
! width=55|Women
! width=55|Total
|-
| align=left|Athletics
| 6 || 0 || 6
|-
| align=left|Boxing
| 4 || – || 4
|-
| align=left|Cycling
| 4 || 1 || 5
|-
| align=left|Diving
| 2 || 1 || 3
|-
| align=left|Fencing
| 1 || 0 || 1
|-
| align=left|Gymnastics
| 0 || 1 || 1
|-
| align=left|Judo
| 6 || 2 || 8
|-
| align=left|Sailing
| 1 || 0 || 1
|-
| align=left|Shooting
| 1 || 1 || 2
|-
| align=left|Swimming
| 5 || 0 || 5
|-
| align=left|Synchronized swimming
| – || 2 || 2
|-
| align=left|Table tennis
| 0 || 2 || 2
|-
| align=left|Taekwondo
| 0 || 1 || 1
|-
| align=left|Tennis
| 2 || 2 || 4
|-
| align=left|Triathlon
| 1 || 0 || 1
|-
| align=left|Weightlifting
| 1 || 1 || 2
|-
| align=left|Wrestling
| 2 || – || 2
|-
! Total || 36 || 14 || 50
|}
Athletics
In total, six Venezuelan athletes participated in the athletics events – José Carabalí, Juan Morillo, Hely Ollarves and José Peña in the men's 4 × 100 m relay and José Alejandro Semprún and Carlos Tarazona in the men's marathon.