2,4,6-Trinitrophenylmethylnitramine or tetryl (C<sub>7</sub>H<sub>5</sub>N<sub>5</sub>O<sub>8</sub>) is an explosive compound used to make detonators and explosive booster charges.

Tetryl is a nitramine booster explosive, though its use has been largely superseded by RDX. Tetryl is a sensitive secondary high explosive used as a booster, a small charge placed next to the detonator in order to propagate detonation into the main explosive charge.

Chemical properties

Tetryl is a yellow crystalline solid powder material, practically insoluble in water but soluble in acetone, benzene and other solvents. When tetryl is heated, it first melts, then decomposes and explodes. It burns readily and is more easily detonated than ammonium picrate or TNT, being about as sensitive as picric acid. It is detonated by friction, shock, or spark. It remains stable at all temperatures which may be encountered in storage. It is generally used in the form of pressed pellets, and has been approved as the standard bursting charge for small-caliber projectiles, since it gives much better fragmentation than TNT. It has an explosive velocity of . Tetryl is the basis for the service tetryl blasting caps necessary for positive detonation of TNT. A mixture of mercury fulminate and potassium chlorate is included in the cap to ensure detonation of tetryl.

Dutch chemist Karel Hendrik Mertens originally synthesized the compound as a part of his doctoral dissertation published in 1877 by slowly mixing dimethylaniline with concentrated nitric acid in the presence of sulfuric acid, and it's still a viable lab technique. However, in the 1930s a more economical route was commercialized, where methylamine produced by the Smoleński method (developed after WWI) reacts with dinitrochlorobenzene to make dinitromethylaniline which is then easily nitrated without byproducts.

Health concerns

Although tetryl is among the most toxic explosive compounds, it is very short-lived, especially if in fact detonated. This combined with the fact that the health impacts of this compound are largely unstudied, not much is known about any health problems that this compound may cause.

Epidemiological data shows that tetryl has most effect on the skin, acting as a strong irritant. Symptoms of skin sensitization such as dermatitis, itch, erythema, etc. may occur. Tetryl can also affect mucous membranes, the upper respiratory tract, and possibly the liver.

See also

  • Hexanitrobenzene
  • Trinitrotoluene
  • RE factor

References

  • Cooper, Paul W., Explosives Engineering, New York: Wiley-VCH, 1996.
  • Tetryl, Agency for Toxic Substances and Disease Registry
  • Occupational Safety and Health Guideline for Tetryl , Occupational Safety & Health Administration