thumb|343px|right|Global variation in soil pH. <br />

Soil pH is a measure of the acidity or basicity (alkalinity) of a soil. Soil pH is a key characteristic that can be used to make informative analysis both qualitative and quantitatively regarding soil characteristics. pH is defined as the negative logarithm (base&nbsp;10) of the activity of hydronium ions ( or, more precisely, ) in a solution. In soils, it is measured in a slurry of soil mixed with water (or a salt solution, such as &nbsp;), and normally falls between 3 and 10, with 7 being neutral. Acidic soils have a pH below 7 and alkaline soils have a pH above 7. Ultra-acidic soils (pH < 3.5) and very strongly alkaline soils (pH > 9) are rare.

Soil pH is considered a master variable in soils as it affects many chemical processes. It specifically affects plant nutrient availability by controlling the chemical forms of the different nutrients and influencing the chemical reactions they undergo. The optimum pH range for most plants is between 5.5 and 7.5.

Classification of soil pH ranges

The United States Department of Agriculture Natural Resources Conservation Service classifies soil pH ranges as follows:

{|class="wikitable" style="align: center;"

!Semantic description

!pH range

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|Ultra acidic|| < 3.5

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|Extremely acidic|| 3.5–4.4

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|Very strongly acidic|| 4.5–5.0

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|Strongly acidic|| 5.1–5.5

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|Moderately acidic|| 5.6–6.0

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|Slightly acidic|| 6.1–6.5

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|Neutral|| 6.6–7.3

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|Slightly alkaline|| 7.4–7.8

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|Moderately alkaline|| 7.9–8.4

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|Strongly alkaline|| 8.5–9.0

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|Very strongly alkaline|| > 9.0

|-

|}

Determining pH

Methods of determining pH include:

  • Observation of soil profile: certain profile characteristics can be indicators of either acid, saline, or sodic conditions. Examples are:
  • Poor incorporation of the organic surface layer with the underlying mineral layer – this can indicate strongly acidic soils;
  • The classic podzol horizon sequence, since podzols are strongly acidic: in these soils, a pale eluvial (E) horizon lies under the organic surface layer and overlies a dark B horizon;
  • Presence of a caliche layer indicates the presence of calcium carbonates, which are present in alkaline conditions;
  • Columnar structure can be an indicator of sodic condition.
  • Observation of predominant flora. Calcifuge plants (those that prefer an acidic soil) include Erica, Rhododendron and nearly all other Ericaceae species, many birch (Betula), foxglove (Digitalis), gorse (Ulex spp.), and Scots pine (Pinus sylvestris). Calcicole (lime loving) plants include ash trees (Fraxinus spp.), honeysuckle (Lonicera), Buddleja, dogwoods (Cornus spp.), lilac (Syringa) and Clematis species. This observational method has been used to calibrate Ellenberg's reaction indicator values.
  • Use of an inexpensive pH testing kit, wherein a small sample of soil is mixed with indicator solution which changes colour according to the acidity.
  • Use of litmus paper. A small sample of soil is mixed with distilled water, into which a strip of litmus paper is inserted. If the soil is acidic the paper turns red, if basic, blue.
  • Certain other fruit and vegetable pigments also change colour in response to changing pH. Blueberry juice turns more reddish if acid is added, and becomes indigo if titrated with sufficient base to yield a high pH. Red cabbage is similarly affected.
  • Use of a commercially available electronic pH meter, in which a electrode or solid-state electrode is inserted into moistened soil or a mixture (suspension) of soil and water; the pH is usually read on a digital display screen.
  • In the 2010s, spectrophotometric methods were developed to measure soil pH involving addition of an indicator dye to the soil extract. These compare well to glass electrode measurements but offer substantial advantages such as lack of drift, liquid junction and suspension effects.

Precise, repeatable measures of soil pH are required for scientific research and monitoring. This generally entails laboratory analysis using a standard protocol; an example of such a protocol is that in the USDA Soil Survey Field and Laboratory Methods Manual. In this document the three-page protocol for soil pH measurement includes the following sections: Application; Summary of Method; Interferences; Safety; Equipment; Reagents; and Procedure.