An electret (formed as a portmanteau of electr- from "electricity" and -et from "magnet") is a dielectric material that has a quasi-permanent electrical polarisation. An electret has internal and external electric fields, and is the electrostatic equivalent of a permanent magnet.
The term electret was coined by Oliver Heaviside for a (typically dielectric) material which has electrical charges of opposite sign at its extremities. Some materials with electret properties were already known to science and had been studied since the early 1700s. One example is the electrophorus, a device consisting of a slab with electret properties and a separate metal plate. The electrophorus was originally invented by Johan Carl Wilcke in Sweden in 1762 and improved by Alessandro Volta in Italy in 1775. The first documented case of production was by Mototarô Eguchi in 1925 who melted a suitable dielectric material such as a polymer or wax that contained polar molecules, and then allowed it to solidify in a powerful electric field. The polar molecules of the dielectric align themselves to the direction of the electric field, producing a dipole electret with a quasi-permanent polarization. Modern electrets are sometimes made by embedding excess charges into a highly insulating dielectric, e.g. using an electron beam, corona discharge, injection from an electron gun, electric breakdown across a gap, or a dielectric barrier.
Electret types
There are two types of electrets:
- Real-charge electrets which contain excess free charges such as electrons or electron holes of one or both polarities which can move around, either
- on the dielectric's surfaces (a surface charge)
- within the dielectric's volume (a space charge)
- Space charge electrets with internal bipolar charges known as ferroelectrets.
- Oriented-dipole electrets contain oriented (aligned) dipoles. These contain bound charges at their surface, which are not free to move around.