Bytownite is a calcium rich member of the plagioclase solid solution series of feldspar minerals with composition between anorthite and labradorite. It is usually defined as having between 70 and 90%An (formula: ). Like others of the series, bytownite forms grey to white triclinic crystals commonly exhibiting the typical plagioclase twinning and associated fine striations.

The specific gravity of bytownite varies between 2.74 and 2.75. The refractive indices ranges are nα=1.563 – 1.572, nβ=1.568 – 1.578, and nγ=1.573 – 1.583. Precise determination of these two properties with chemical, X-ray diffraction, or petrographic analysis are required for identification.

Occurrence

thumb|left|Bytownite from [[Crystal Bay Township, Minnesota|Crystal Bay, Minnesota]]

Bytownite is a rock forming mineral occurring in mafic igneous rocks such as gabbros and anorthosites. It also occurs as phenocrysts in mafic volcanic rocks. It is rare in metamorphic rocks. It is typically associated with pyroxenes and olivine. and named for an occurrence at Bytown (now Ottawa), Canada.